Any should show all the datastore in the vCenter so long as it's still attached to your provider vDC.
If you remove the Any (*) profile from a provider, you cannot add it back in because it's a temporary placeholder until you create actual storage profiles/classes.
Also note:
1. For vCenter 5.1.x you create the Storage Profiles in the C# client.
2. For vCenter 5.5.x you create the Storage Classes and tags in the Web Client.
the process, generally speaking:
- create tag
- assign tag to datastores
- assign tag to profile
- enable storage profiles on the cluster
Once created and tagged, you would add the Profile to the Provider vDC (Manage/Monitor > Provider > double click it > Storage Profiles > [ + ] ). you might have to formally refresh storage profiles from vCenter section first, and wait a few minutes for things to update in the database.